Chapter 5 of 8

Chemistry — Matter, Elements & Periodic Table

States of matter, atomic structure basics, and the organisation of the Periodic Table — foundational Chemistry for every Railway exam.

📖 ~13 min read 🔬 Railways General Science

Introduction

Matter, Elements, and the Periodic Table form the structural foundation of Chemistry — this chapter covers states of matter, basic atomic structure, and how the Periodic Table organises all known elements.

States of Matter

StateShapeVolumeParticle Arrangement
SolidFixedFixedTightly packed, strong forces
LiquidTakes shape of containerFixedClose but able to move past each other
GasTakes shape of containerNot fixedWidely spaced, weak forces, free movement
PlasmaNot fixedNot fixedIonised gas — the fourth state of matter (e.g., inside the Sun)

Changes of State

ChangeProcess
Solid → LiquidMelting
Liquid → SolidFreezing
Liquid → GasVaporisation (Evaporation/Boiling)
Gas → LiquidCondensation
Solid → Gas (directly)Sublimation
📌 Sublimation Examples: Camphor, naphthalene balls, and solid CO₂ (dry ice) all sublime directly from solid to gas without passing through the liquid state.

Atomic Structure — Basic Particles

ParticleChargeLocationRelative Mass
ProtonPositive (+)Nucleus1
NeutronNeutral (0)Nucleus1
ElectronNegative (−)Orbits around nucleus~1/1836 (negligible)
TermDefinition
Atomic Number (Z)Number of protons in an atom (defines the element)
Mass Number (A)Number of protons + neutrons
IsotopesAtoms of the same element with the same atomic number but different mass numbers (different neutron count)

Elements, Compounds, and Mixtures

TermDefinitionExample
ElementPure substance made of only one type of atomOxygen, Iron, Gold
CompoundTwo or more elements chemically combined in a fixed ratioWater (H₂O), Salt (NaCl)
MixtureTwo or more substances physically combined, no fixed ratio, can be separatedAir, salt water

The Periodic Table — Organisation

📌 Modern Periodic Law: Elements are arranged in order of increasing atomic number. Elements in the same column (group) share similar chemical properties.
TermDescription
GroupsVertical columns (18 total) — elements share similar valence electron configuration
PeriodsHorizontal rows (7 total) — elements have the same number of electron shells
MetalsMajority of elements; good conductors, malleable, ductile, lustrous (left/centre of table)
Non-MetalsPoor conductors, brittle if solid (right side of table)
MetalloidsProperties intermediate between metals and non-metals (e.g., Silicon, Boron)

Important Element Groups

GroupNameProperty
Group 1Alkali MetalsHighly reactive metals (Li, Na, K)
Group 17HalogensHighly reactive non-metals (F, Cl, Br, I)
Group 18Noble GasesChemically inert/unreactive (He, Ne, Ar)
Q. An atom has 11 protons and 12 neutrons. Find its atomic number and mass number.
Atomic Number = number of protons = 11 (this is Sodium)
Mass Number = protons + neutrons = 11+12 = 23
Exam Focus: Four states of matter and their particle arrangement · Changes of state (including sublimation examples) · Proton/neutron/electron properties · Atomic number vs mass number · Groups vs periods in the Periodic Table · Metal/non-metal/metalloid classification.

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